Chlorido(2-iminomethyl-3-fluorophenyl-κ2C1,N)tris(trimethylphosphane-κP)iron [Fe(C7H5FN)Cl(C3H9P)3]
2011
Iron Complex with Chlorido and Trimethylphosphane
publication
Evidence: moderate
Author Information
Author(s): Xu Xiaofeng, Li Xiaoyan
Primary Institution: Shandong University
Hypothesis
Can iron complexes activate C-Cl bonds effectively?
Conclusion
The study demonstrates that iron(0) complexes can easily activate C-Cl bonds, leading to the formation of iron(II) chloride complexes.
Supporting Evidence
- The iron atom in the compound has an octahedral coordination geometry.
- A five-membered chelate ring is formed during the reaction.
- The study provides insights into C-Cl bond activation mechanisms.
Takeaway
This study shows that a special iron compound can break a bond with chlorine, which might help in making new chemicals.
Methodology
The compound was synthesized by reacting Fe(PMe3)4 with (2-chloro-6-fluorophenyl)methanimine in diethyl ether, followed by crystallization.
Limitations
The compound is sensitive to air and decomposes quickly upon exposure.
Digital Object Identifier (DOI)
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