cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ2 N,N′]bis­(dimethyl sulfoxide-κO)cadmium [Cd(C10H9N4O2S)2(C2H6OS)2]
2011

Cadmium Complex with Sulfadiazine

publication Evidence: moderate

Author Information

Author(s): G. M. Golzar Hossain

Primary Institution: University of Dhaka

Hypothesis

The study aims to prepare a cadmium(II) complex with sulfadiazine in methanol.

Conclusion

The cadmium complex exhibits a distorted trigonal-prismatic coordination geometry and is stabilized by hydrogen bonding.

Supporting Evidence

  • The cadmium complex is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules.
  • The crystal structure features intermolecular hydrogen bonds that lead to the formation of layers.

Takeaway

The researchers made a new compound using cadmium and sulfadiazine, which has a special shape and sticks together with the help of tiny connections called hydrogen bonds.

Methodology

The sodium salt of sulfadiazine was reacted with a cadmium salt in methanol, followed by crystallization from dimethylsulfoxide.

Digital Object Identifier (DOI)

10.1107/S1600536811010816

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