catena-Poly[[[(2,2′-bipyridine-κ2N,N′)(dimethyl sulfoxide-κO)(nitrato-κ2O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ4O1,O1′:O3,O3′] dimethyl sulfoxide monosolvate]
2011

New Coordination Polymer with Bismuth

publication Evidence: moderate

Author Information

Author(s): Pasdar Hoda, Namegh Marjan, Aghabozorg Hossein, Notash Behrouz

Primary Institution: Islamic Azad University, North Tehran Branch

Conclusion

The study presents a new one-dimensional coordination polymer involving bismuth, bipyridine, and a tricarboxylic acid.

Supporting Evidence

  • The compound exhibits a distorted tricapped trigonal-prismatic geometry.
  • Hydrogen bonds stabilize the crystal packing of the compound.
  • The polymeric structure is extended by HBTC2- moieties.

Takeaway

Scientists created a new material using bismuth and some special chemicals, and it forms a unique structure that could be useful in science.

Methodology

The compound was synthesized by reacting bismuth(III) nitrate, bipyridine, and 1,3,5-benzenetricarboxylic acid in DMSO and ethanol.

Digital Object Identifier (DOI)

10.1107/S1600536811005745

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