Acrinathrin: (S)-cyano(3-phenoxyphenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoromethyl)ethoxycarbonyl]vinyl}cyclopropane-1-carboxylate
2011
Crystal Structure of Acrinathrin
publication
Evidence: moderate
Author Information
Author(s): Yang Hojin, Kim Tae Ho, Park Ki-Min, Kim Jineun
Primary Institution: Gyeongsang National University
Conclusion
The crystal structure of acrinathrin was successfully determined, revealing specific dihedral angles and intermolecular interactions that contribute to its stability.
Supporting Evidence
- The dihedral angle between the cyclopropane ring plane and the vinyl group plane is 79.3°.
- Weak intermolecular C—H···F hydrogen bonds and C—H···π interactions were observed in the crystal structure.
- All bond lengths and angles in the structure are normal and comparable to similar compounds.
Takeaway
Scientists studied a chemical called acrinathrin to see how its molecules are arranged in a crystal. They found that the way the molecules are positioned helps keep the crystal stable.
Methodology
The title compound was purchased and single crystals were obtained through slow evaporation of a solution in CH2Cl2 for X-ray analysis.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website