Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
2011

Unexpected Product from a Chemical Reaction

publication

Author Information

Author(s): Wang Hongwei, Hu Yimin

Primary Institution: Anhui Normal University

Conclusion

The reaction of ethyl 3-bromo-3-phenylpropanoate with pentane-2,4-dione produced a racemic crystal structure of C16H20O4.

Supporting Evidence

  • The compound C16H20O4 contains one chiral carbon atom.
  • The crystal structure is racemic due to the presence of inversion centers.
  • Weak C—H⋯O interactions contribute to the crystal packing.

Takeaway

Scientists mixed some chemicals and found a new compound that has a special structure with two types of molecules in it.

Methodology

The reaction was conducted in a Schlenk flask under nitrogen at 373 K for 22 hours.

Digital Object Identifier (DOI)

10.1107/S160053681100955X

Want to read the original?

Access the complete publication on the publisher's website

View Original Publication