Propane-1,2-diaminium tris­(pyridine-2,6-dicarboxyl­ato-κ3O2,N,O6)zirconate(IV) trihydrate
2011

Crystal Structure of a Zirconium Complex

publication Evidence: high

Author Information

Author(s): Pasdar Hoda, Shakiba Shahrzad, Aghabozorg Hossein, Notash Behrouz

Primary Institution: Islamic Azad University, North Tehran Branch

Hypothesis

The study investigates the crystal structure of a new zirconium complex formed with propane-1,2-diamine and pyridine-2,6-dicarboxylic acid.

Conclusion

The crystal structure reveals that the zirconium(IV) ion is coordinated by three pyridine-2,6-dicarboxylate ligands in a distorted tricapped trigonal prismatic geometry.

Supporting Evidence

  • The zirconium(IV) ion is chelated by three pyridine-2,6-dicarboxylate anions.
  • The crystal structure is stabilized by intermolecular hydrogen bonds.

Takeaway

Scientists made a new compound using zirconium and some special acids, and they found out how the atoms are arranged in it.

Methodology

The compound was synthesized by reacting zirconium chloride with propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in water, followed by crystallization through slow evaporation.

Digital Object Identifier (DOI)

10.1107/S1600536811008488

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