Preparation and Characterization of Poly(vinyl-alcohol)/Chitosan Polymer Blend Films Chemically Crosslinked with Glutaraldehyde: Mechanical and Thermal Investigations
2024

Poly(vinyl-alcohol)/Chitosan Polymer Blend Films

publication Evidence: moderate

Author Information

Author(s): Pugar Daniel, Haramina Tatjana, Leskovac Mirela, Ćurković Lidija

Primary Institution: Department of Polytechnic, Dr. Franjo Tuđman Defense and Security University, Croatia

Hypothesis

The addition of chitosan and glutaraldehyde will improve the mechanical and barrier properties of poly(vinyl-alcohol) films.

Conclusion

The study found that adding chitosan and glutaraldehyde improves the barrier properties of poly(vinyl-alcohol) films.

Supporting Evidence

  • The addition of chitosan reduces the crystallinity of poly(vinyl-alcohol), leading to improved barrier properties.
  • Crosslinking with glutaraldehyde enhances the mechanical properties of the polymer blend.
  • Dynamic mechanical analysis showed that the addition of chitosan increases the intensity of α relaxation.

Takeaway

Mixing chitosan with poly(vinyl-alcohol) makes the material better at keeping gases out, which is good for packaging.

Methodology

The films were prepared using the solvent casting method and analyzed using dynamic mechanical analysis, differential scanning calorimetry, and the time-lag permeation technique.

Limitations

The study did not analyze pure chitosan due to its brittleness.

Digital Object Identifier (DOI)

10.3390/molecules29245914

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