4-Bromo-N,N'-diphenylbenzimidamide N′-oxide
2024
4-Bromo-N,N'-diphenylbenzimidamide N'-oxide
publication
Evidence: moderate
Author Information
Author(s): Saha Arindam, Chartrand Daniel, Cibian Mihaela, Maris Thierry, Hanan Garry S.
Primary Institution: Département de Chimie, Université de Montréal
Hypothesis
The study explores the formation of earth-abundant transition-metal complexes of amidine oxides to study their photophysical and redox properties.
Conclusion
The crystal structure of the compound reveals electronic delocalization in the N—C—N moieties and the presence of hydrogen bonds linking dimers.
Supporting Evidence
- The compound crystallizes in the orthorhombic Pna21 space group with two molecules in the asymmetric unit.
- The N—C—N bond lengths indicate electronic delocalization.
- Hydrogen bonds link the molecules into cyclic dimers.
Takeaway
The researchers made a new compound and looked at how its structure works, finding that parts of it can share electrons.
Methodology
The compound was synthesized using a modified procedure and its crystal structure was determined through X-ray diffraction.
Digital Object Identifier (DOI)
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