Rapid Thermal Shutdown of Deep‐Eutectic‐Polymer Electrolyte Enabling Overheating Self‐Protection of Lithium Metal Batteries
2024

Rapid Thermal Shutdown of Deep‐Eutectic‐Polymer Electrolyte for Lithium Metal Batteries

Sample size: 1 publication 10 minutes Evidence: high

Author Information

Author(s): Zhang Zengqi, Li Gang, Du Xiaofan, Huang Lang, Kang Guohong, Zhang Jianjun, Cui Zili, Liu Tao, Ni Ling, Jin Yongcheng, Cui Guanglei

Primary Institution: Ocean University of China

Hypothesis

Can a deep-eutectic-polymer electrolyte with thermal shutdown capability improve the safety of lithium metal batteries?

Conclusion

The deep-eutectic-polymer electrolyte significantly enhances the thermal safety and electrochemical performance of lithium metal batteries.

Supporting Evidence

  • The new electrolyte improves the self-heating temperature from 73 °C to 172 °C.
  • It prolongs the thermal runaway waiting time by more than 20 hours.
  • The polymer electrolyte retains 92% capacity over 200 cycles in one battery type.
  • Another battery type maintains 90% capacity after 500 cycles.

Takeaway

This study shows that a special type of battery gel can stop working when it gets too hot, which helps prevent fires and explosions.

Methodology

The study involved creating a deep-eutectic-polymer electrolyte and testing its thermal and electrochemical properties in lithium metal batteries.

Limitations

The study does not address long-term stability or performance under various environmental conditions.

Digital Object Identifier (DOI)

10.1002/advs.202409628

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