Zwitterionic (E)-1-[(4-nitro­phen­yl)iminio­meth­yl]naphthalen-2-olate
2011

Synthesis and Structure of a Zwitterionic Schiff Base Compound

publication Evidence: moderate

Author Information

Author(s): Damous Maamar, Hamlaoui Meriem, Bouacida Sofiane, Merazig Hocine, Daran Jean-Claude

Primary Institution: Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Université Mentouri-Constantine

Hypothesis

The study investigates the synthesis and crystal structure of a zwitterionic Schiff base compound.

Conclusion

The synthesized compound crystallizes in a zwitterionic form and exhibits a planar molecular structure with significant hydrogen bonding interactions.

Supporting Evidence

  • The compound was synthesized through a reaction involving 2-hydroxy-1-naphthaldehyde and 4-nitrobenzenamine.
  • The crystal structure shows significant hydrogen bonding interactions.
  • The molecular structure is essentially planar with a small dihedral angle.
  • Intermolecular hydrogen bonds form layers in the crystal structure.

Takeaway

The researchers made a new chemical compound by mixing two ingredients, and they found that it forms a special structure with strong connections between its parts.

Methodology

The compound was synthesized by refluxing a mixture of 2-hydroxy-1-naphthaldehyde and 4-nitrobenzenamine in methanol, followed by recrystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811012359

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