Bis{N,N-bis[(diphenylphosphanyl)methyl]aniline-κ2P,P′}copper(I) tetrafluoridoborate [Cu(C32H29NP2)2]BF4
2011
Copper(I) Complex with Phosphine Ligands
publication
Evidence: moderate
Author Information
Author(s): Shang Jing, Huang Li-Li, Huang Ting-Hong, Ma Kai, Ni Qing-Ling
Primary Institution: Guangxi Normal University
Hypothesis
The study investigates the synthesis and crystal structure of a new mononuclear copper(I) complex.
Conclusion
The copper(I) complex exhibits a distorted tetrahedral geometry and forms chains in the crystal structure through various interactions.
Supporting Evidence
- The copper(I) atom is coordinated by four phosphorus atoms from two phosphine ligands.
- Intramolecular and intermolecular hydrogen bonds are present in the crystal structure.
- The study contributes to the understanding of copper(I) complexes with phosphine ligands.
Takeaway
Scientists made a new copper compound that has a special shape and sticks together in a unique way.
Methodology
The compound was synthesized by mixing [Cu(CH3CN)4]BF4 with N,N-bis[(diphenylphosphanyl)methyl]aniline in acetonitrile, followed by slow diffusion of diethyl ether.
Digital Object Identifier (DOI)
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