1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
2011

Synthesis of a New Ligand for Metal-Organic Frameworks

publication Evidence: moderate

Author Information

Author(s): Wei Tai-Bao, Lu Yan-Yun, Cao Cheng, Yao Hong, Zhang You-Ming

Primary Institution: Northwest Normal University

Hypothesis

The title compound is designed to be a tridentate ligand for constructing metal-organic frameworks.

Conclusion

The synthesized compound has potential as a ligand for creating diverse coordination polymers.

Supporting Evidence

  • The compound has three benzimidazole groups that can act as coordination sites.
  • The synthesis yielded colorless crystals suitable for X-ray diffraction analysis.

Takeaway

Scientists made a new chemical that can help build special structures called metal-organic frameworks, which can be used for various applications.

Methodology

The compound was synthesized by reacting 1H-benzimidazole with sodium hydroxide and tetrakis(bromomethyl)methane in a solvent mixture, followed by recrystallization.

Limitations

The structure contains disordered solvent molecules that could not be located.

Digital Object Identifier (DOI)

10.1107/S1600536811023464

Want to read the original?

Access the complete publication on the publisher's website

View Original Publication