L-Cysteine/Silver Nitrate/Iodate Anions System: Peculiarities of Supramolecular Gel Formation with and Without Visible-Light Exposure
2024

Study of Supramolecular Gel Formation with L-Cysteine and Iodate Anions

publication Evidence: moderate

Author Information

Author(s): Vishnevetskii Dmitry V., Polyakova Elizaveta E., Andrianova Yana V., Mekhtiev Arif R., Ivanova Alexandra I., Averkin Dmitry V., Alekseev Vladimir G., Bykov Alexey V., Sulman Mikhail G.

Primary Institution: Tver State University

Hypothesis

Can iodate anions act as both a gelling and photosensitive agent in a cysteine-silver sol system?

Conclusion

The study found that iodate anions can initiate gel formation and enhance the gel's photosensitivity, leading to significant changes in viscosity and color upon light exposure.

Supporting Evidence

  • The gels formed in the dark were weak and snot-like, but became stronger and changed color when exposed to light.
  • Iodate anions were found to be selective in their interaction with the cysteine-silver sol compared to other anions.
  • Visible light exposure led to significant changes in the viscosity and morphology of the gels.
  • X-ray photoelectron spectroscopy confirmed the presence of silver iodide and silver oxide nanoparticles in the gel structure.

Takeaway

This research shows that a special gel made from cysteine and silver can change when light hits it, which could help detect certain chemicals.

Methodology

The study used various physico-chemical methods including viscosimetry, UV spectroscopy, and electron microscopy to analyze gel formation and properties.

Digital Object Identifier (DOI)

10.3390/gels10120809

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