Diiodidobis[4-(4-nitro­benz­yl)pyridine-κN1]zinc [ZnI2(C12H10N2O2)2]
2011

Structure of a Zinc Iodide Complex with a Nitrobenzylpyridine Ligand

publication Evidence: moderate

Author Information

Author(s): Smith Graham, Wermuth Urs D., Williams Michael L.

Primary Institution: Queensland University of Technology

Conclusion

The study reports the crystal structure of a zinc iodide complex with a substituted pyridine ligand, revealing its distorted tetrahedral geometry.

Supporting Evidence

  • The compound was synthesized from zinc(II) iodide and a nitrobenzylpyridine ligand.
  • The crystal structure shows two independent distorted tetrahedral complex units.
  • Intermolecular interactions were observed in the crystal packing.

Takeaway

The researchers made a new compound by mixing zinc iodide with a special type of pyridine, and they found that it has a unique shape.

Methodology

The compound was synthesized by heating zinc(II) iodide with 4-(4-nitrobenzyl)pyridine in ethanol-water, followed by X-ray analysis.

Digital Object Identifier (DOI)

10.1107/S1600536811005939

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