N,N′-Dibenzyl-2,2′-(3,6-dioxaoctane-1,8-diyldi­oxy)dibenzamide
2011

Study of a New Acyclic Polyether Compound

publication Evidence: moderate

Author Information

Author(s): Wen Yong-Hong, Dai Ji-Min

Primary Institution: College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology

Hypothesis

The study investigates the synthesis and structural properties of a new flexible acyclic polyether ligand.

Conclusion

The title compound crystallizes in a monoclinic space group and exhibits a unique folded conformation due to intramolecular hydrogen bonding.

Supporting Evidence

  • The compound crystallizes with one half-molecule in the asymmetric unit.
  • The dihedral angle between the benzene rings is 86.19°.
  • An intramolecular hydrogen bond forms a six-membered ring affecting the molecule's conformation.
  • The crystal packing is stabilized by intermolecular interactions.

Takeaway

Scientists made a new type of molecule that can bend in a special way, which helps it stick to other things better.

Methodology

The compound was synthesized using a literature method and characterized using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811002212

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