2-Meth­oxy­anilinium 3-hy­droxy-2,4,6-trinitro­phenolate
2011

Study of a Molecular Salt from 2-Methoxyaniline and Styphnic Acid

publication Evidence: moderate

Author Information

Author(s): Kalaivani Doraisamyraja, Malarvizhi Rangasamy, Thanigaimani Kaliyaperumal, Muthiah Packianathan Thomas

Primary Institution: Seethalakshmi Ramaswami College, Tiruchirappalli, Tamil Nadu, India

Hypothesis

Can 2-methoxyaniline and styphnic acid form a stable molecular salt?

Conclusion

The study successfully demonstrates the formation of a stable molecular salt through charge-transfer interactions between 2-methoxyaniline and styphnic acid.

Supporting Evidence

  • The title compound is linked via hydrogen bonds.
  • The molecular salt was obtained with a yield of 70-75%.
  • Good pale yellow crystals were formed by slow evaporation of ethanol.

Takeaway

The researchers mixed two chemicals to make a new solid that sticks together really well. This new solid is made from 2-methoxyaniline and styphnic acid.

Methodology

The molecular salt was prepared by dissolving styphnic acid and 2-methoxyaniline in dimethyl sulphoxide, mixing them, and then crystallizing the product.

Digital Object Identifier (DOI)

10.1107/S1600536811005708

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