μ-4,4′-Bipyridine-κ2N:N′-bis[bis(2-chlorobenzoato-κ2O,O′)lead(II)] [Pb2(C7H4ClO2)4(C10H8N2)]
2011
New Lead(II) Complex with 2-Chlorobenzoate and 4,4'-Bipyridine
publication
Evidence: high
Author Information
Author(s): Feng Tian-Jun
Primary Institution: Lanzhou Jiaotong University
Hypothesis
The study investigates the crystal structure of a new Pb(II) complex formed from 2-chlorobenzoic acid, 4,4'-bipyridine, and lead(II) acetate.
Conclusion
The crystal structure reveals a dinuclear complex with specific coordination geometry and stabilizing interactions.
Supporting Evidence
- The PbII atom is coordinated by four O atoms and one N atom.
- The coordination environment is hemidirected.
- The structure is stabilized by hydrogen bonds and π–π stacking interactions.
Takeaway
Scientists created a new compound using lead and certain organic molecules, and they looked at how these parts fit together in a special way.
Methodology
The compound was synthesized in an alkaline aqueous solution and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
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