Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ3O2,N,O6)mercurate(II) dihydrate
2011

Structure of a Mercury Compound with Pyridine Ligands

publication Evidence: moderate

Author Information

Author(s): Agah Ali Akbar, Saadati Moshtaghin Hamid Reza, Notash Behrouz, Amiri Rudbari Hadi, Bruno Giuseppe

Primary Institution: Faculty of Chemistry, Tarbiat Moallem University

Conclusion

The study presents the crystal structure of a mercury compound coordinated by pyridine-2,6-dicarboxylate ligands, stabilized by various noncovalent interactions.

Supporting Evidence

  • The mercury ion is coordinated by four oxygen and two nitrogen atoms from the ligands.
  • The structure contains two uncoordinated water molecules.
  • Hydrogen bonds and π–π stacking interactions stabilize the crystal structure.

Takeaway

Scientists studied a special mercury compound that has some pyridine parts in it, and they found out how the parts stick together in a certain way.

Methodology

The compound was synthesized by mixing an aqueous solution of propane-1,2-diamine, pyridine-2,6-dicarboxylic acid, and mercury(II) nitrate, and crystals were obtained after three weeks.

Digital Object Identifier (DOI)

10.1107/S1600536811024366

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