catena-Poly[[[aqua­(formato-κO)(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-formato-κ2 O:O′] monohydrate] [Mn(HCO2)2(C12H8N2)(H2O)]·H2O
2011

New Manganese(II) Complex with Formate and Phenanthroline

publication Evidence: moderate

Author Information

Author(s): Wei Xu

Primary Institution: Ningbo University

Hypothesis

The study investigates the self-assembly of manganese(II) ions with 1,10-phenanthroline and formic acid to form a new coordination polymer.

Conclusion

The new manganese(II) complex exhibits a one-dimensional zigzag chain structure and forms a three-dimensional network through hydrogen bonding and π-π stacking interactions.

Supporting Evidence

  • The complex consists of polymeric chains of manganese ions bridged by formate anions.
  • The chains are extended into a three-dimensional network via hydrogen bonding and π-π stacking interactions.
  • The study contributes to the understanding of coordination polymers and their potential applications.

Takeaway

Scientists created a new compound using manganese and some special chemicals, and it forms a unique structure that could be useful for making new materials.

Methodology

The compound was synthesized by mixing manganese chloride with sodium hydroxide, followed by the addition of 1,10-phenanthroline and formic acid, and allowing the solution to evaporate slowly to form crystals.

Digital Object Identifier (DOI)

10.1107/S1600536811020575

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