Metal-Organic Papers[Rb(18-crown-6)][Rb([2.2.2]-cryptand)]Rb2Sn9·5NH3
2011

New Crystal Structure of a Rubidium-Stannide Compound

publication Evidence: high

Author Information

Author(s): Gaertner Stefanie, Korber Nikolaus

Primary Institution: Institut für Anorganische Chemie, Universität Regensburg

Conclusion

The study presents the first ammoniate of a Zintl anion with a new structural motif formed by large chelating molecules.

Supporting Evidence

  • The compound represents the first ammoniate of a Zintl anion.
  • Two different chelating substances were involved in the crystal structure.
  • The new structural motif consists of one-dimensional double strands.

Takeaway

Scientists discovered a new type of crystal made from rubidium and tin that has a unique structure thanks to special molecules that help hold it together.

Methodology

The crystal structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536811013997

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