Role of Aspartate 42 and Histidine 79 in the aiPLA2 activity and oligomeric status of Prdx6 at low pH
2024

How Two Amino Acids Affect a Protein's Function at Low pH

publication Evidence: moderate

Author Information

Author(s): Kakchingtabam Pushpa, Shahnaj Sharifun, Kumari Anju, Longjam Japani, Wungnaopam A. N., Herojit Khundrakpam, Laishram Rajendrakumar Singh, Fisher Aron B., Rahaman Hamidur

Primary Institution: Manipur University

Hypothesis

The formation of electrostatic interaction driven by the protonation of His79 and Asp42 because of lowering pH is necessary for the oligomerization process of Prdx6.

Conclusion

The study found that the amino acids Asp42 and His79 are crucial for the oligomerization and aiPLA2 activity of Prdx6 at low pH.

Supporting Evidence

  • The wild type Prdx6 forms higher oligomers at low pH, which is essential for its aiPLA2 activity.
  • Mutations at Asp42 and His79 significantly reduce aiPLA2 activity at low pH.
  • The study utilized dynamic light scattering and size exclusion chromatography to analyze protein oligomerization.

Takeaway

This study shows that two specific parts of a protein help it change shape and work better when the environment is more acidic.

Methodology

The study used site-directed mutagenesis to create mutants of Prdx6 and analyzed their activity and oligomeric status at different pH levels.

Digital Object Identifier (DOI)

10.21203/rs.3.rs-5129146

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