The crystal structures of methyl prop-2-ynoate, dimethyl fumarate and their protonated species
2025

Crystal Structures of Methyl Prop-2-ynoate and Dimethyl Fumarate

publication Evidence: high

Author Information

Author(s): Hollenwäger Dirk, Bockmair Valentin, Kornath Andreas J.

Primary Institution: Ludwig-Maximilians Universität

Hypothesis

The study investigates the crystal structures of methyl prop-2-ynoate, dimethyl fumarate, and their protonated species.

Conclusion

The first single-crystal structures of methyl prop-2-ynoate and the protonated species of dimethyl fumarate were successfully characterized.

Supporting Evidence

  • Methyl prop-2-ynoate was crystallized for the first time.
  • The protonated species of both esters were isolated and characterized.
  • Single-crystal X-ray diffraction confirmed the structures of the compounds.

Takeaway

Scientists looked at the structures of two chemicals and found new forms of them that had never been seen before.

Methodology

The compounds were crystallized and characterized using single-crystal X-ray diffraction and Raman spectroscopy.

Digital Object Identifier (DOI)

10.1107/S2053229624011653

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