catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
2011
Synthesis and Structure of a Manganese-Containing Coordination Polymer
publication
Evidence: moderate
Author Information
Author(s): Liu Wei, Zhang Gang
Primary Institution: Department of Chemistry and Chemical Engineering, Henan University of Urban Construction, Pingdingshan, Henan, People’s Republic of China
Conclusion
The study presents the synthesis and crystal structure of a manganese-containing coordination polymer with a distorted octahedral geometry.
Supporting Evidence
- The manganese ion in the compound has a distorted octahedral coordination geometry.
- The study utilized X-ray single-crystal diffraction analysis to determine the structure.
- The compound exhibits a three-dimensional network of hydrogen bonds that stabilize its crystal packing.
Takeaway
The researchers made a new compound that includes manganese and studied its structure using X-ray techniques.
Methodology
The compound was synthesized from a methanol solution of di-2-pyridylamine and manganese chloride, followed by the addition of a ferrocene-containing dicarboxylic acid.
Digital Object Identifier (DOI)
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