Bis(μ-3,5-difluorobenzoato)bis[(3,5-difluorobenzoato)dimethyltin(IV)] [Sn2(CH3)4(C7H3F2O2)4]
2011

Crystal Structure of a Tin Complex

publication Evidence: moderate

Author Information

Author(s): Liu Hong, Yin Han-Dong, Li Jing, Wang Da-Qi

Primary Institution: Liaocheng University, Shandong, People’s Republic of China

Hypothesis

The study aims to synthesize and characterize a new organotin compound.

Conclusion

The synthesized compound exhibits a distorted pentagonal bipyramidal coordination geometry around the tin atom.

Supporting Evidence

  • The compound was synthesized and characterized successfully.
  • The tin atom is in a distorted pentagonal bipyramidal coordination geometry.
  • The molecular structure forms a dimer linked by hydrogen bonds.

Takeaway

Scientists made a new tin compound and looked at its structure. They found that the tin is shaped like a weird pyramid with five sides.

Methodology

The compound was synthesized using 3,5-difluorobenzoic acid, sodium ethoxide, and dimethyltin dichloride, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810054061

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