Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato)nickelate(II) penta­hydrate
2011

Study of a Nickel Complex with Benzene-1,3-diammonium and Pyridine-2,6-dicarboxylate

publication Evidence: moderate

Author Information

Author(s): Pasdar Hoda, Sadat Kashani Saghi, Aghabozorg Hossein, Notash Behrouz

Primary Institution: Islamic Azad University, North Tehran Branch

Conclusion

The study presents a nickel complex with a distorted octahedral geometry stabilized by hydrogen bonds and π-π interactions.

Supporting Evidence

  • The nickel ion in the compound is coordinated by two nitrogen and four oxygen atoms.
  • The crystal structure is stabilized by various types of hydrogen bonds.
  • Intermolecular interactions include π-π stacking between aromatic rings.

Takeaway

Scientists created a new nickel compound and found that it has a special shape and is held together by tiny forces called hydrogen bonds.

Methodology

The compound was synthesized by mixing solutions of pyridine-2,6-dicarboxylic acid, benzene-1,3-diamine, and nickel chloride, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810054371

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