[Zn(CH5N3S)2(C2H6OS)](C6H2N3O7)2·C2H6OS·H2O
2011

Zinc Thiosemicarbazide Complex Structure

publication Evidence: moderate

Author Information

Author(s): Shanthakumari R., Hema Ramu, Ramamurthy K., Sridar Balasubramnian, Stoeckli-Evans Helen

Primary Institution: Department of Physics, Government Arts College for Women, Pudukottai, Tamil Nadu, India

Conclusion

The study presents the crystal structure of a zinc thiosemicarbazide complex, revealing its unique coordination and hydrogen bonding interactions.

Supporting Evidence

  • The zinc atom in the complex is five-coordinated in a distorted square-pyramidal geometry.
  • Hydrogen bonds link the molecules into two-dimensional networks, forming a three-dimensional arrangement.
  • The study provides insights into the conformational preferences of thiosemicarbazide in metal-complex formation.

Takeaway

Scientists studied a special zinc compound that has thiosemicarbazide in it, and they found out how the atoms are arranged and connected.

Methodology

The compound was synthesized from a mixture of thiosemicarbazide, picric acid, and zinc chloride, followed by crystallization from DMSO.

Limitations

Positional disorder was observed in some components of the structure.

Digital Object Identifier (DOI)

10.1107/S160053681005378X

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