Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate
2011
Study of Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate
publication
Evidence: moderate
Author Information
Author(s): Keleşoğlu Zeynep, Gültekin Zeynep, Büyükgüngör Orhan
Primary Institution: Ondokuz Mayıs University
Conclusion
The study presents the crystal structure of a compound with a unique half-boat conformation and specific hydrogen bonding interactions.
Supporting Evidence
- The compound exhibits a half-boat conformation with specific puckering parameters.
- Intramolecular N—H⋯O hydrogen bonding generates an S(6) ring motif.
- Weak intermolecular C—H⋯O hydrogen bonds link molecules into zigzag chains.
Takeaway
The researchers looked at a special chemical compound and found out how its atoms are arranged and how they stick together.
Methodology
The compound was synthesized using a method involving 2'-aminoacetophenone and Bi(OTf)3, followed by purification and crystallization.
Digital Object Identifier (DOI)
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