Poly[[diaqua(μ2-1,4-dioxane-κ2 O:O′)(μ2-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato-κ2 O 1:O 4)copper(II)] 1,4-dioxane disolvate dihydrate]
2011
Copper Coordination Polymer with Dioxane
publication
Evidence: moderate
Author Information
Author(s): Yu Jing, Zhang Yi-Feng, Sun Fu-An, Chen Qun
Primary Institution: Jiangsu Polytechnic University
Hypothesis
The study investigates the solvent template effect of 1,4-dioxane in the construction of coordination polymers.
Conclusion
The title compound forms a three-dimensional supramolecular network through hydrogen bonding and coordination.
Supporting Evidence
- The CuII ion is six-coordinated by oxygen donors from ligands and water.
- Each BDC-F4 anion bridges two CuII ions, forming a chain.
- The structure features hydrogen bonds connecting layers.
Takeaway
This study shows how a special liquid called dioxane helps create a new type of material with copper that has a unique structure.
Methodology
The compound was synthesized by mixing an aqueous solution of Cu(ClO4)2.6H2O with a dioxane solution of H2BDC-F4 and allowing it to crystallize.
Digital Object Identifier (DOI)
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