Assessing the efficiency of danacid as corrosion inhibitor for aluminium in HCl medium: Experimental, theoretical and optimization studies
2024

Using Expired Danacid to Prevent Aluminium Corrosion in Acid

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Author Information

Author(s): O.D. Onukwuli, I.A. Nnanwube, F.O. Ochili, J.I. Obibuenyi

Primary Institution: Nnamdi Azikiwe University, Madonna University

Hypothesis

Can expired danacid effectively inhibit the corrosion of aluminium in hydrochloric acid?

Conclusion

Expired danacid is an effective inhibitor for aluminium corrosion in hydrochloric acid, achieving an inhibition efficiency of up to 95.05%.

Supporting Evidence

  • The inhibition efficiency increased with higher concentrations of danacid.
  • Electrochemical tests showed danacid acted as a mixed-type inhibitor.
  • DFT results indicated effective adsorption of danacid on aluminium surfaces.

Takeaway

The study found that expired danacid can help protect aluminium from rusting in acid, making it a useful and eco-friendly option.

Methodology

The study used gravimetric, electrochemical, and density functional theory (DFT) techniques to assess the corrosion inhibition efficiency of expired danacid.

Limitations

The study primarily focused on one type of acid (HCl) and may not be generalizable to other corrosive environments.

Statistical Information

P-Value

p<0.05

Statistical Significance

p<0.05

Digital Object Identifier (DOI)

10.1016/j.heliyon.2024.e40994

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