Cyanidotetrakis(trimethylphosphine)cobalt(I) [Co(CN)(C3H9P)4]
2011
Cyanidotetrakis(trimethylphosphine)cobalt(I)
publication
Author Information
Author(s): Xu Xiaofeng, Feng Lei, Li Xiaoyan
Primary Institution: Shandong University
Conclusion
The compound [Co(CN)(C3H9P)4] is stable in air for several hours but decomposes rapidly in solution at room temperature.
Supporting Evidence
- The cobalt(I) atom has a trigonal-bipyramidal coordination environment.
- The compound was obtained through a specific chemical reaction.
- It decomposes rapidly in solution at room temperature.
Takeaway
Scientists made a new cobalt compound that can stay in the air for a little while but breaks down quickly when it's in a liquid.
Methodology
The compound was synthesized by reacting [Co(PMe3)4] with 2,6-difluorobenzonitrile in diethyl ether, followed by crystallization.
Digital Object Identifier (DOI)
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