Poly[diaqua­tris­(μ4-1,3-phenyl­ene­diacetato)­dicerium(III)] [Ce2(C10H8O4)3(H2O)2]
2011

New Lanthanide Coordination Polymer Structure

publication Evidence: moderate

Author Information

Author(s): Gao Zhu-Qing, Li Hong-Jin, Gu Jin-Zhong

Primary Institution: Taiyuan University of Science and Technology

Hypothesis

The study aims to investigate the crystal structure of a new lanthanide coordination polymer using 1,3-phenylendiacetic acid as a ligand.

Conclusion

The study successfully synthesized and characterized a new lanthanide coordination polymer with a complex three-dimensional structure.

Supporting Evidence

  • The new polymer features a distorted tricapped trigonal-prismatic coordination geometry.
  • Eight cerium ions and twelve ligands form a large ring structure.
  • The study contributes to the understanding of lanthanide coordination compounds.

Takeaway

Scientists created a new material using special chemicals that can form a unique structure, which might be useful for various applications.

Methodology

The polymer was synthesized by reacting cerium nitrate with a ligand in a sealed container at high temperature.

Digital Object Identifier (DOI)

10.1107/S1600536811003801

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