trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ2N1,S)cadmium dipicrate dihydrate
2011

Crystal Structure of a Cadmium Complex

publication Evidence: moderate

Author Information

Author(s): Shanthakumari R., Hema R., Ramamurthy K., Stoeckli-Evans Helen

Primary Institution: Government Arts College for Women, Pudukkottai, India

Conclusion

The cadmium(II) complex crystallizes as a dihydrate and forms a three-dimensional network through hydrogen bonding.

Supporting Evidence

  • The cadmium(II) atom is hexa-coordinated in an octahedral fashion.
  • The complex is stabilized by hydrogen bonds and weak interactions.
  • The synthesis involved a reaction of thiosemicarbazide, picric acid, and cadmium bromide.

Takeaway

Scientists made a special crystal using cadmium and some other chemicals, and they found that the crystal has a unique structure that holds together with tiny connections called hydrogen bonds.

Methodology

The compound was synthesized by reacting thiosemicarbazide, picric acid, and cadmium bromide in a specific molar ratio, followed by recrystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810053602

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