[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ2 P:P′]decacarbonyl-1κ3 C,2κ3 C,3κ4 C-triangulo-triruthenium(0)–methanol (8/1) 8[Ru3(C29H30P2)(CO)10]·CH4O
2011
Structure of a Triangulo-Triruthenium Complex
publication
Evidence: moderate
Author Information
Author(s): Shawkataly Omar bin, Khan Imthyaz Ahmed, Hafiz Malik H. A., Yeap Chin Sing, Fun Hoong-Kun
Primary Institution: Universiti Sains Malaysia
Hypothesis
The study aims to synthesize and characterize a new metal-organic compound involving triangulo-triruthenium.
Conclusion
The synthesized compound exhibits a unique structure with specific ligand arrangements and intermolecular interactions.
Supporting Evidence
- The compound contains two triangulo-triruthenium molecules and a methanol solvent molecule.
- The phosphine ligand bridges an Ru—Ru bond and is equatorial with respect to the Ru3 triangle.
- The dihedral angles between the two benzene rings attached to each P atom are consistent across the two molecules.
Takeaway
The researchers made a new chemical compound with three ruthenium atoms and studied how it is structured and how it interacts with other molecules.
Methodology
The compound was synthesized using standard Schlenk techniques and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website