Metal-Organic Papers
2011

Crystal Structure of a Metal-Organic Compound

publication Evidence: moderate

Author Information

Author(s): Aghabozorg Hossein, Omidvar Sara, Mirzaei Masoud, Notash Behrouz

Primary Institution: Islamic Azad University, North Tehran Branch, Tehran, Iran

Conclusion

The study presents the synthesis and detailed crystal structure of a new metal-organic compound featuring a one-dimensional anionic complex and extensive hydrogen bonding.

Supporting Evidence

  • The compound features a one-dimensional anionic complex with two nine-coordinate CeIII ions.
  • Extensive intermolecular hydrogen bonds stabilize the crystal structure.
  • The geometry around the cerium atoms is described as highly distorted tricapped trigonal-prismatic.

Takeaway

Scientists made a new compound that has special structures and bonds, which help hold it together. They used certain chemicals and found that it forms a unique shape.

Methodology

The compound was synthesized by mixing cerium nitrate with pyridine-2,6-dicarboxylic acid and 4,4'-bipyridine in water, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811004995

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