5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniumcyclotetradecadiene diiodide dihydrate
2011

Structure of a New Organic Compound

publication Evidence: moderate

Author Information

Author(s): Alan R. Kennedy, Samwel T. Lutta, Catriona A. Morrison, Maurice O. Okoth, Daniel M. Orang’o

Primary Institution: University of Strathclyde

Conclusion

The compound is isostructural with its bromide analogue and features a unique sheet structure due to hydrogen bonding.

Supporting Evidence

  • The compound contains a macrocyclic dication with centrosymmetric symmetry.
  • Intermolecular hydrogen bonding forms eight-membered rings that create a sheet structure.
  • Packing analysis showed that the compound is isostructural with its bromide analogue.

Takeaway

Scientists studied a new chemical compound to see how it is structured, and they found it is similar to another compound they already knew about.

Methodology

The compound was synthesized using ethylenediamine and hydroiodic acid, followed by crystallization and analysis using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811005848

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