Visible Light-Driven Direct Z-Scheme Ho2SmSbO7/YbDyBiNbO7 Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion
2024

Efficient Degradation of Fenitrothion Using a New Photocatalyst

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Author Information

Author(s): Hao Liang, Luan Jingfei, SolĂ­s-Casados Dora Alicia

Primary Institution: School of Physics, Changchun Normal University; State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University

Hypothesis

Novel single-crystal photocatalysts, namely Ho2SmSbO7 and YbDyBiNbO7, would display superior photocatalytic performance through the strategic substitution of elements within Bi2InTaO7.

Conclusion

The HYO heterojunction demonstrated exceptional photocatalytic performance, achieving a 99.83% removal efficiency for fenitrothion.

Supporting Evidence

  • HYO achieved a removal efficiency of 99.83% for fenitrothion.
  • HYO outperformed other photocatalysts, achieving removal rates that were 1.10, 1.20, and 2.97 times higher than Ho2SmSbO7, YbDyBiNbO7, and N-doped TiO2, respectively.
  • HYO demonstrated a mineralization rate of 98.77% for total organic carbon during the degradation process.
  • Trapping experiments identified hydroxyl radicals, superoxide anions, and holes as active species in the degradation process.

Takeaway

Scientists created a new material that can clean up a harmful pesticide from water using light, and it works really well!

Methodology

The HYO heterojunction was synthesized using an ultrasonic-assisted solvent thermal method and its photocatalytic performance was evaluated under visible light.

Limitations

The study primarily focuses on the degradation of fenitrothion and may not address other pollutants.

Digital Object Identifier (DOI)

10.3390/molecules29245930

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