Redetermination of AgPO3
2011

Redetermination of AgPO3

publication Evidence: high

Author Information

Author(s): Terebilenko Katherina V., Zatovsky Igor V., Ogorodnyk Ivan V., Baumer Vyacheslav N., Slobodyanik Nikolay S.

Primary Institution: Taras Shevchenko National University

Conclusion

The study confirms previous findings about the structure of AgPO3 with higher precision and refined displacement parameters.

Supporting Evidence

  • The structure of AgPO3 features two types of distorted edge- and corner-sharing AgO5 polyhedra.
  • The study achieved a significant improvement in the precision of the structural data compared to previous studies.
  • The bond-valence sum values indicate a degree of silver 'underbonding' affecting the physical properties.

Takeaway

The researchers studied a compound called AgPO3 and found that its structure is more precise than earlier studies showed.

Methodology

Single crystals of AgPO3 were prepared using a phosphoric acid melt method, and the structure was analyzed using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811003977

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