Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN1]copper(II) dihydrate
2011

Copper(II) Complex with Water and Triazole Ligands

publication Evidence: moderate

Author Information

Author(s): Xu Shuzhi, Shao Wenxin, Yu Miao, Gong Guihua

Primary Institution: Jilin Business and Technology College

Conclusion

The study presents a copper(II) complex that exhibits a distorted octahedral geometry and forms a three-dimensional supramolecular network through hydrogen bonding.

Supporting Evidence

  • The CuII atom is six-coordinated by two N atoms and four water molecules.
  • Intermolecular hydrogen bonds create a three-dimensional network.
  • Intra­molecular hydrogen bonds and π–π interactions are also present.

Takeaway

Scientists created a special copper compound that has water and other molecules attached to it, and they found that these molecules help hold everything together in a unique way.

Methodology

The compound was synthesized by mixing 4-(1,2,4-triazol-4-yl)benzoic acid, NaOH, and CuCl2·2H2O in water, followed by crystallization from the filtrate.

Digital Object Identifier (DOI)

10.1107/S1600536811018356

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