Metal-Organic Papers
2011

Structure of a Nickel Complex with Ligands

publication Evidence: moderate

Author Information

Author(s): Ayikoé Kouassi, Butcher Ray J., Gultneh Yilma

Primary Institution: Department of Chemistry, Howard University

Conclusion

The study presents the crystal structure of a nickel(II) complex with specific ligands, revealing its octahedral coordination and hydrogen bonding interactions.

Supporting Evidence

  • The nickel atom is coordinated in an octahedral geometry.
  • There are hydrogen-bonding interactions between the secondary amine and phenolate.
  • The dihedral angle between the aromatic rings is 80.23°.
  • Intermolecular interactions link the molecules into chains.

Takeaway

Scientists studied a nickel complex to see how it is structured. They found that it has a special shape and bonds that help it stay together.

Methodology

The complex was synthesized using salicylaldehyde and 2-benzylaminopyridine, followed by crystallization and X-ray diffraction analysis.

Digital Object Identifier (DOI)

10.1107/S1600536811001425

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