Poly[μ-aqua-aqua{μ-6-ethoxy-2-[(2-isonicotinoylhydrazinylidene)methyl]phenolato-κ3 O,N,O′}dioxidosodiumvanadate(V)] [NaV(C15H13N3O3)O2(H2O)2]
2011
New Vanadium Compound with Schiff Base Ligand
publication
Evidence: moderate
Author Information
Author(s): Wong Hon Wee, Lo Kong Mun, Ng Seik Weng
Primary Institution: University of Malaya
Conclusion
The study presents a new vanadium(V) compound that exhibits a unique five-coordination geometry and forms a three-dimensional network through hydrogen bonding.
Supporting Evidence
- The vanadium atom in the compound is coordinated in a trigonal-bipyramidal geometry.
- The compound forms a three-dimensional network through hydrogen bonds.
- The study utilized X-ray crystallography to determine the structure.
Takeaway
Scientists created a new type of vanadium compound that connects in a special way, making it stable and interesting for further study.
Methodology
The compound was synthesized using a condensation reaction of isonicotinic acid hydrazide and 3-ethoxysalicyldehyde, followed by reaction with vanadyl(IV) sulfate and sodium acetate.
Digital Object Identifier (DOI)
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