Bis[4-(dimethyl­amino)­pyridinium] tetra­chloridozincate
2011

Structure of a Hybrid Material with Zinc and Dimethylamino Pyridine

publication Evidence: moderate

Author Information

Author(s): Kefi Riadh, Lefebvre Frederic, Zeller Matthias, Ben Nasr Cherif

Primary Institution: Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Tunisia

Conclusion

The study reveals the molecular and crystal structure of a hybrid material formed by zinc and dimethylamino pyridine, held together by various intermolecular interactions.

Supporting Evidence

  • The compound consists of [ZnCl4]2− anions and 4-(dimethyl­amino)­pyridinium cations.
  • Intermolecular interactions include hydrogen bonding and π–π stacking.
  • The structure forms a three-dimensional network due to these interactions.

Takeaway

Scientists studied a special material made of zinc and a type of nitrogen compound, showing how they stick together in a unique way.

Methodology

The compound was synthesized by evaporating a mixture of 4-(dimethylamino)pyridine, zinc chloride, and HCl, followed by X-ray diffraction analysis.

Digital Object Identifier (DOI)

10.1107/S1600536811005010

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