2-[(Meth­oxy­carbonothio­yl)sulfan­yl]acetic acid
2011

Study of 2-(Methoxycarbonothioylthio)acetic Acid

publication Evidence: moderate

Author Information

Author(s): Xiao Shude, Charpentier Paul A.

Primary Institution: The University of Western Ontario

Hypothesis

Can 2-(methoxycarbonothioylthio)acetic acid be used as a chain transfer agent in RAFT polymerization?

Conclusion

The study successfully prepared poly(vinyl acetate)s containing carboxylic acid end groups using 2-(methoxycarbonothioylthio)acetic acid as a chain transfer agent.

Supporting Evidence

  • 2-(methoxycarbonothioylthio)acetic acid was successfully used in RAFT polymerization.
  • The study provides insights into the structure and properties of the compound.
  • Previous studies indicated that xanthates can promote fragmentation of unstable radicals.

Takeaway

This study shows that a specific chemical can help make new types of plastics by controlling how they grow.

Methodology

The compound was synthesized using potassium hydroxide and carbon disulfide, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811003941

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