(N-Benzyl-N-ethyl­dithio­carbamato)di-tert-butyl­chloridotin(IV) [Sn(C4H9)2Cl(C10H12NS2)]
2011

Study of a Tin Compound with Dithiocarbamate Ligand

publication Evidence: moderate

Author Information

Author(s): Abdul Muthalib Amirah Faizah, Baba Ibrahim, Mohamed Tahir Mohamed Ibrahim, Tiekink Edward R. T.

Primary Institution: Universiti Kebangsaan Malaysia

Hypothesis

The study investigates the coordination geometry and crystal structure of a specific diorganotin dithiocarbamate compound.

Conclusion

The compound exhibits a coordination geometry that is intermediate between square pyramidal and trigonal bipyramidal.

Supporting Evidence

  • The SnIV atom in the compound is penta-coordinated.
  • The coordination geometry is defined by a unique arrangement of ligands.
  • C–H···π interactions lead to dimeric aggregates in the crystal structure.

Takeaway

The researchers looked at a tin compound and found that it has a unique shape and structure that could be important for its use in medicine or agriculture.

Methodology

The compound was synthesized and its crystal structure was analyzed using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811006398

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