Bis(2-amino-6-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
2011

New Cu(II) Complex with Pyrazine-2,3-Dicarboxylic Acid

publication Evidence: moderate

Author Information

Author(s): Eshtiagh-Hosseini Hossein, Hassanpoor Azam, Mirzaei Masoud, Szymańska-Buzar Teresa, Kochel Andrzej

Primary Institution: Ferdowsi University of Mashhad

Conclusion

The study presents a new Cu(II) complex that exhibits a three-dimensional supramolecular structure due to extensive hydrogen bonding and π–π stacking interactions.

Supporting Evidence

  • The CuII atom is located on an inversion centre and has an overall octahedral coordination environment.
  • Extensive classical and non-classical hydrogen bonds contribute to the compound's stability.
  • The compound was characterized using X-ray diffraction techniques.

Takeaway

Scientists created a new compound using copper and certain acids, which forms a special structure that could be useful in future applications.

Methodology

The compound was synthesized by refluxing a solution of pyrazine-2,3-dicarboxylic acid and 2-amino-6-methylpyridine with CuCl2·2H2O in water.

Digital Object Identifier (DOI)

10.1107/S1600536811008981

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