Poly[bis­(μ2-4,4′-bipyridine)­bis­(3-nitro­benzoato)nickel(II)] [Ni(C7H4NO4)2(C10H8N2)2]
2011

Structure of a Nickel Coordination Polymer

publication Evidence: moderate

Author Information

Author(s): Hsu Shih-Chen, Lo Sheng-Han, Kao Ching-Che, Lin Chia-Her

Primary Institution: Chung-Yuan Christian University

Hypothesis

The study investigates the synthesis and crystal structure of a nickel coordination polymer with specific ligands.

Conclusion

The nickel coordination polymer exhibits a two-dimensional layer structure with specific bond lengths and interactions.

Supporting Evidence

  • The crystal structure analysis reveals a two-dimensional layer structure.
  • The average bond lengths of Ni—O and Ni—N are within expected ranges.
  • The layers interact through π-π interactions between benzene rings.

Takeaway

The researchers made a special type of crystal using nickel and some organic materials, and they found that it has a layered structure.

Methodology

The synthesis involved hydrothermal reactions at 453 K for 3 days, followed by slow cooling.

Digital Object Identifier (DOI)

10.1107/S1600536810050117

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