Metal-Organic Papers (Acetato-κO)bis(1,10-phenanthroline-κ2N,N′)copper(II) acetate heptahydrate [Cu(C2H3O2)(C12H8N2)2](C2H3O2)·7H2O
2011
Copper(II) Complex with 1,10-Phenanthroline
publication
Evidence: moderate
Author Information
Author(s): Jing Buqin, Li Lianzhi, Dong Jianfang, Xu Tao
Primary Institution: College of Chemistry and Chemical Engineering, Shanxi Datong University
Hypothesis
The study investigates the structure of a copper(II) complex formed with 1,10-phenanthroline and acetate.
Conclusion
The copper(II) complex exhibits a five-coordinate distorted square-pyramidal geometry.
Supporting Evidence
- The central CuII ion is five coordinate, bound to four N atoms and one O atom.
- The complex forms a two-dimensional polymeric structure through hydrogen bonding.
- Blue block-shaped crystals suitable for X-ray diffraction were obtained.
Takeaway
The researchers created a special copper compound that has a unique shape and structure, which could be useful for making new materials.
Methodology
The complex was synthesized by reacting cupric acetate monohydrate with 1,10-phenanthroline in an aqueous solution.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website