Bromido(meso-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II) bromide dihydrate [CuBr(C16H32N4)]Br·2H2O
2011

Copper Bromide Complex with Water

publication Evidence: moderate

Author Information

Author(s): Shi Fei-Fei, He Xiu-Li

Primary Institution: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing, People’s Republic of China

Conclusion

The study presents the crystal structure of a copper(II) bromide complex with a specific ligand and water molecules.

Supporting Evidence

  • The crystal structure consists of two cations, two bromide anions, and four water molecules.
  • The copper atom is five-coordinate square pyramidal with long Cu—Br bonds.
  • The structure is stabilized by hydrogen bonds forming a chain structure.

Takeaway

Scientists created a special copper compound that includes bromine and water, and they figured out how its atoms are arranged.

Methodology

The compound was synthesized by reacting CuSO4.5H2O with a specific ligand in methanol, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811012852

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