Bis(4-methyl-3,5-diphenyl-1H-pyrazole-κN2)silver(I) nitrate [Ag(C16H14N2)2]NO3
2011
Structure of a Silver Pyrazole Complex
publication
Evidence: moderate
Author Information
Author(s): Hossaini Sadr Moayad, Soltani Behzad, Engle James T., Ziegler Christopher J., Kabirzadeh M.
Primary Institution: Department of Chemistry, Azarbaijan University of Tarbiat Moallem, Tabriz, Iran
Hypothesis
The study aims to synthesize and determine the structure of a silver(I) pyrazole complex.
Conclusion
The crystal structure of the silver pyrazole complex is stabilized by various intermolecular interactions.
Supporting Evidence
- The geometry around the AgI ion is T-shaped with two short Ag—N bonds and one long Ag—O bond.
- The crystal structure is stabilized by intermolecular N—H⋯O, C—H⋯O, and C—H⋯π interactions.
- Single crystals suitable for X-ray diffraction were obtained after 4 days of evaporation.
Takeaway
The researchers made a new silver compound using a special chemical and looked at its structure using X-ray. They found that the silver is shaped like a 'T' and is held together by different types of bonds.
Methodology
The compound was synthesized in acetone and characterized using X-ray diffraction.
Digital Object Identifier (DOI)
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