Chlorido(η5-cyclopentadienyl)[(4a,4b,8a,9,9a-η)-fluorenyl](fluorenyl-κC9)zirconium(IV) toluene solvate [Zr(C5H5)(C13H9)2Cl]·C7H8
2011
Zirconium Complex with Fluorenyl Ligands
publication
Evidence: high
Author Information
Author(s): Łapczuk-Krygier Agnieszka, Ponikiewski Łukasz, Pikies Jerzy
Primary Institution: Gdansk University of Technology
Conclusion
The study presents the crystal structure of a zirconium complex with fluorenyl ligands, revealing its coordination geometry and dihedral angles.
Supporting Evidence
- The zirconium atom is coordinated by a chloride atom, a cyclopentadienyl ligand, and two fluorenyl ligands.
- The dihedral angles between the fluorenyl and cyclopentadienyl rings were measured.
- The study utilized X-ray diffraction to analyze the crystal structure.
Takeaway
Scientists studied a special zirconium compound that has two fluorenyl groups attached to it, and they found out how these groups are arranged around the zirconium atom.
Methodology
The crystal structure was determined using X-ray diffraction techniques.
Digital Object Identifier (DOI)
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