catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ2 O:O′] [Sn(C7H7)3(C7H5O3)]
2011

Structure of a Carboxylate-Bridged Polymer

publication Evidence: high

Author Information

Author(s): Keng Thy Chun, Lo Kong Mun, Ng Seik Weng

Primary Institution: University of Malaya

Conclusion

The study reveals the structure of a carboxylate-bridged polymer with a distorted trigonal-bipyramidal geometry around the tin atom.

Supporting Evidence

  • The tin atom in the polymer exhibits a distorted trigonal-bipyramidal geometry.
  • The polymer structure propagates as a chain along the a-axis.
  • Two independent formula units were identified in the asymmetric unit.

Takeaway

Scientists studied a special type of tin compound that forms long chains. They found out how the atoms are arranged in this chain.

Methodology

The compound was synthesized by heating tribenzyltin hydroxide and furylacrylic acid in ethanol, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811023919

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